{"id":26070,"date":"2024-02-06T08:03:34","date_gmt":"2024-02-06T08:03:34","guid":{"rendered":"https:\/\/science-hub.click\/2%2C4%2C6-%E3%83%88%E3%83%AA%E3%82%AF%E3%83%AD%E3%83%AD%E3%83%95%E3%82%A7%E3%83%8E%E3%83%BC%E3%83%AB-%E5%AE%9A%E7%BE%A9\/"},"modified":"2024-02-06T08:03:34","modified_gmt":"2024-02-06T08:03:34","slug":"2%2C4%2C6-%E3%83%88%E3%83%AA%E3%82%AF%E3%83%AD%E3%83%AD%E3%83%95%E3%82%A7%E3%83%8E%E3%83%BC%E3%83%AB-%E5%AE%9A%E7%BE%A9","status":"publish","type":"post","link":"https:\/\/science-hub.click\/?p=26070","title":{"rendered":"2,4,6-\u30c8\u30ea\u30af\u30ed\u30ed\u30d5\u30a7\u30ce\u30fc\u30eb – \u5b9a\u7fa9"},"content":{"rendered":"

\u5c0e\u5165<\/h2>
2,4,6\u30c8\u30ea\u30af\u30ed\u30ed\u30d5\u30a7\u30ce\u30fc\u30eb<\/th><\/tr>
\n\"2,4,6-\u30c8\u30ea\u30af\u30ed\u30ed\u30d5\u30a7\u30ce\u30fc\u30eb\"<\/figure>
\n\"2,4,6-\u30c8\u30ea\u30af\u30ed\u30ed\u30d5\u30a7\u30ce\u30fc\u30eb\"<\/figure><\/td><\/tr>
\u4e00\u822c\u7684\u306a<\/th><\/tr>
IUPAC\u540d<\/td><\/tr>
\u540c\u7fa9\u8a9e<\/td>\u30d5\u30a7\u30ca\u30af\u30ed\u30eb2,4,6-TCP<\/td><\/tr>
CAS\u756a\u53f7<\/sup><\/td>88-06-2<\/span><\/span><\/td><\/tr>
No.EINECS<\/sup><\/td> 201-795-9<\/span><\/td><\/tr>
\u30d1\u30d6\u30b1\u30e0<\/td>6914<\/span><\/td><\/tr>
\u7b11\u9854<\/td><\/tr>
\u30a4\u30f3\u30c1\u30c1<\/td><\/tr>
\u5916\u89b3<\/td>\u7121\u8272\u304b\u3089\u9ec4\u8272\u306e<\/a><\/span>\u7d50\u6676\u3067\u3001\u7279\u6709\u306e\u81ed\u6c17\u304c\u3042\u308b\u3002<\/td><\/tr>
\u5316\u5b66\u7684\u6027\u8cea<\/th><\/tr>
\u751f\u306e\u30d5\u30a9\u30fc\u30df\u30e5\u30e9<\/td>C 6<\/sub> H 3<\/sub> Cl 3<\/sub> O<\/td><\/tr>
\u30e2\u30eb\u8cea\u91cf<\/a><\/span><\/td>197.446 \u00b1 0.011 g mol -1<\/sup><\/td><\/tr>
pKa<\/td> 6.21\uff08 25<\/span> \u2103<\/abbr> \uff09\u3002<\/td><\/tr>
\u7269\u7406\u7684\u6027\u8cea<\/th><\/tr>
\u878d\u89e3<\/a><\/span>\u6e29\u5ea6<\/td>69.5<\/span> \u2103<\/abbr><\/td><\/tr>
\u6cb8\u9a30<\/a><\/span>\u6e29\u5ea6<\/td>240<\/span> \u2103<\/abbr><\/td><\/tr>
\u6eb6\u89e3\u6027<\/td>0.8<\/span> g<\/span> \u00b7 l<\/span> -1<\/sup><\/span> ( 25<\/span> \u00b0C)<\/abbr><\/td><\/tr>
\u5bc6\u5ea6<\/a><\/span><\/td>1.675<\/span> g<\/span> cm<\/span> -3<\/sup><\/span> ( 25<\/span> \u00b0C)<\/abbr><\/td><\/tr>
\u5f15\u706b\u70b9<\/a><\/span><\/td>99<\/span> \u2103<\/abbr><\/td><\/tr>
\u98fd\u548c\u84b8\u6c17\u5727<\/a><\/span><\/td>0.035<\/span> mbar<\/span><\/span> ( 20<\/span> \u00b0C)<\/abbr> 0.07<\/span> mbar<\/span><\/span> ( 30<\/span> \u00b0C)<\/abbr> 50<\/span> \u00b0C<\/abbr>\u30670.25<\/span> mbar<\/span><\/span><\/td><\/tr>
\u4e88\u9632<\/th><\/tr>
\u6307\u4ee4 67\/548\/EEC <\/center><\/td><\/tr>
\n\"\u6709\u5bb3\"<\/figure> Xn <\/center><\/td>
\n\"\u74b0\u5883\u306b\u3068\u3063\u3066\u5371\u967a\"<\/figure> N<\/center><\/td><\/tr><\/table><\/td><\/tr>
R\u30d5\u30ec\u30fc\u30ba\uff1a 22\u300136<\/span> \/38\u300140\u300150<\/span> \/ 53<\/span> \u3001<\/span><\/td><\/tr>
S\u30d5\u30ec\u30fc\u30ba: (2)\u3001<\/span> 36\/<\/span> 37\u300160\u300161<\/span> \u3001<\/span><\/td><\/tr>
\u4ea4\u901a\u6a5f\u95a2<\/a><\/span><\/center><\/td><\/tr>
60<\/span><\/center><\/td><\/tr>
2020\u5e74<\/span><\/center><\/td><\/tr><\/table><\/center><\/td><\/tr>
WHMIS\u3002 <\/center><\/td><\/tr>
\n\"D1B:<\/figure><\/center> D1B\u3001<\/span> D2B\u3001<\/span><\/td><\/tr>
GHS\u3002 <\/center><\/td><\/tr>
\n\"SGH09:<\/figure>\u6ce8\u610f<\/center>H302\u3001<\/span> H315\u3001<\/span> H319\u3001<\/span> H351\u3001<\/span> H410\u3001<\/span><\/td><\/tr>
\u751f\u614b\u6bd2\u6027\u5b66<\/th><\/tr>
DL<\/td> 820<\/span> mg<\/span>\u30fbkg<\/span> -1<\/sup><\/span> (\u30e9\u30c3\u30c8\u3001\u7d4c\u53e3)<\/td><\/tr>
\u30ed\u30b0P<\/td> 3.87<\/td><\/tr>
\u7279\u306b\u6307\u5b9a\u306e<\/a><\/span>\u306a\u3044\u9650\u308a\u3001SI \u304a\u3088\u3073 CNTP \u5358\u4f4d\u3002<\/center><\/td><\/tr><\/table>

2,4,6-\u30c8\u30ea\u30af\u30ed\u30ed\u30d5\u30a7\u30ce\u30fc\u30eb<\/b>(2,4,6-TCP \u3068\u3082\u547c\u3070\u308c\u307e\u3059) \u306f\u3001\u5316\u5b66\u5f0f C 6<\/sub> H 3<\/sub> Cl 3<\/sub> O 1<\/sub>\u306e\u30af\u30ed\u30ed\u30d5\u30a7\u30ce\u30fc\u30eb\u3067\u3059\u3002\u3053\u308c\u306f\u6728\u6750\u306e\u4fdd\u5b58\u306b\u4f7f\u7528\u3055\u308c\u308b\u6bba\u83cc\u5264\u3067\u3042\u308b\u3060\u3051\u3067\u306a\u304f\u3001\u591a\u304f\u306e\u5316\u5408\u7269\u306e\u5408\u6210\u306e\u4e2d\u9593\u4f53\u3068\u3057\u3066\u3082\u4f7f\u7528\u3055\u308c\u307e\u3059\u3002\u767a\u304c\u3093\u6027\u304c\u7591\u308f\u308c\u3066\u3044\u307e\u3059\u3002<\/p>

\u4f7f\u7528<\/h2>

\u6728\u6750\u3092\u4fdd\u5b58\u3059\u308b\u6bba\u83cc\u5264\u3067\u3042\u308a\u3001\u30d5\u30a7\u30ce\u30fc\u30eb\u3088\u308a\u3082\u5f37\u529b\u306a\u9632\u8150\u5264<\/a><\/span>\u3067\u3059\u3002\u307e\u305f\u3001\u30da\u30f3\u30bf\u30af\u30ed\u30ed\u30d5\u30a7\u30ce\u30fc\u30eb<\/a><\/span>\u30842,3,4,6-\u30c6\u30c8\u30e9\u30af\u30ed\u30ed\u30d5\u30a7\u30ce\u30fc\u30eb<\/span>\u306a\u3069\u306e\u690d\u7269\u691c\u75ab\u88fd\u54c1\u306e\u88fd\u9020\u306e\u4e2d\u9593\u4f53\u3068\u3057\u3066\u3082\u4f7f\u7528\u3055\u308c\u307e\u3059\u3002<\/p>

\u305d\u306e\u88fd\u9020\u30d7\u30ed\u30bb\u30b9\u304c2,3,7-\u30c8\u30ea\u30af\u30ed\u30ed\u30b8\u30d9\u30f3\u30be-p-\u30b8\u30aa\u30ad\u30b7\u30f3<\/span>\u3001 1,3,7,9-\u30c6\u30c8\u30e9\u30af\u30ed\u30ed\u30b8\u30d9\u30f3\u30be-p-\u30b8\u30aa\u30ad\u30b7\u30f3<\/span>\u3001 1,3\u3001 6,8-\u30c6\u30c8\u30e9\u30af\u30ed\u30ed\u30b8\u30d9\u30f3\u30be-p-\u30c0\u30a4\u30aa\u30ad\u30b7\u30f3<\/span>\u3001\u304a\u3088\u30732,3,7,8-\u30c6\u30c8\u30e9\u30af\u30ed\u30ed\u30b8\u30d9\u30f3\u30be\u30d5\u30e9\u30f3<\/span>\u3084\u30dd\u30ea\u30af\u30ed\u30ed\u30b8\u30d9\u30f3\u30be\u30d5\u30e9\u30f3\u306a\u3069\u306e\u4ed6\u306e\u6c5a\u67d3\u7269\u8cea\u3002<\/p>

\u5b89\u5b9a\u6027\/\u52a3\u5316<\/h2>

2005 INERIS \u30b7\u30fc\u30c8\u306b\u3088\u308b\u3068\u30012,4,6-\u30c8\u30ea\u30af\u30ed\u30ed\u30d5\u30a7\u30ce\u30fc\u30eb\u306f\u7d2b\u5916\u7dda\u306e\u5f71\u97ff\u3067\u5206\u89e3\u3055\u308c\u307e\u3059 (\u534a\u6e1b\u671f = 17 \u6642\u9593) (Freitag et al., 1982)\u3002\u6c34\u4e2d<\/a><\/span>\u3001\u5ec3\u6c34\u51e6\u7406\u65bd\u8a2d\u304b\u3089\u306e\u5fae\u751f\u7269\u306e\u5b58\u5728\u4e0b\uff08Tabak et al.\u30011981\uff09\u3001\u307e\u305f\u306f\u571f\u58cc\u4e2d\u3067\u571f\u58cc\u5fae\u751f\u7269\uff0895\uff05\uff09\u306b\u3088\u308a100<\/span> \u03bcg<\/span> \u00b7 g<\/span>\u306e\u5272\u5408\u3067 3 \u65e5\u3067\u5206\u89e3\u3055\u308c\u307e\u3059\u3002 1 \u306f<\/sup><\/span>\u6e7f\u3063\u305f\u30b7\u30eb\u30c8\u7c98\u571f\u8cea\u306e\u571f\u58cc (Baker \u3068 Mayfield\u30011980) \u3067\u3059\u304c\u3001\u5acc\u6c17\u6027<\/a><\/span>\u74b0\u5883\u3067\u306f\u751f\u5206\u89e3\u3055\u308c\u307e\u305b\u3093 (WHO IPCS\u30011989; Baker \u3068 Mayfield\u30011980)\u3002<\/p>

\u751f\u7523\u3068\u5408\u6210<\/h2>

\u30d5\u30a7\u30ce\u30fc\u30eb\u306e\u5b58\u5728\u4e0b\u3001\u5869\u7d20<\/a><\/span>\u30ac\u30b9\u3067\u5869\u7d20\u5316\u3059\u308b\u3053\u3068\u306b\u3088\u308a\u5f97\u3089\u308c\u307e\u3059\u3002<\/p>

\u751f\u614b\u6bd2\u6027<\/h2>

\u3053\u308c\u306f\u5730\u8868<\/a><\/span>\u6c34\u306e\u6c5a\u67d3\u7269\u8cea<\/a><\/span>\u3067\u3042\u308a\u3001\u7a0b\u5ea6\u306f\u4f4e\u3044\u3067\u3059\u304c\u5927\u6c17\u306e\u6c5a\u67d3<\/a><\/span>\u7269\u8cea\u3067\u3042\u308a\u3001\u6c34\u751f\u690d\u7269\u306b\u3088\u3063\u3066\u751f\u7269\u6fc3\u7e2e\u3055\u308c\u308b\u53ef\u80fd\u6027\u304c\u3042\u308a\u307e\u3059 (\u9678\u751f\u7a2e\u306b\u95a2\u3059\u308b\u30c7\u30fc\u30bf\u306f\u3042\u308a\u307e\u305b\u3093)\u3002<\/p>

\u52d5\u7269<\/a><\/span>\uff08\u5b9f\u9a13\u5ba4\uff09\u3067\u306f\u3001\u809d\u81d3<\/a><\/span>\u3068\u814e\u81d3\u304c\u305d\u308c\u3092\u84c4\u7a4d\u3059\u308b\u5668\u5b98\u3067\u3059\u304c\u3001\u8133<\/a><\/span>\u3001\u7b4b\u8089\u3001\u8102\u80aa\u7d44\u7e54\u306b\u3082\u4f4e\u30ec\u30d9\u30eb\u3067\u5b58\u5728\u3057\u307e\u3059\uff08\u534a\u6e1b\u671f\u306f1.4\uff5e1.8\u6642\u9593<\/a><\/span>\uff09\u3002 Pekari et al.\u30011986 \u5e74\u3001INERIS Sheet 2005 \u3067\u5f15\u7528<\/a><\/span>\uff09\u3002<\/p>

\u30e9\u30c3\u30c8<\/a><\/span>\u3067\u306f\u3001\u5b9f\u9a13\u5ba4\u3067\u3001\u80c3\u7ba1<\/a><\/span>\u304b\u308915\u65e5\u9593\u6bce\u65e5<\/a><\/span>\u30011ppm\u306e\u653e\u5c04\u6027\u6a19\u8b58\u3057\u305f<\/span>\u7528\u91cf\u3092\u6295\u4e0e\u3057\u305f<\/a><\/span>(Bahig et al., 1981)\u3002\u751f\u4f53\u84c4\u7a4d\u306f 3\u65e5<\/a><\/span>\u76ee\u306b\u5b89\u5b9a\u3057\u3001\u6bce\u65e5\u6295\u4e0e\u3055\u308c\u308b\u653e\u5c04\u80fd<\/a><\/span>\u306e 92.5% \u304c\u7cde\u4fbf\u4e2d\u306b\u691c\u51fa\u3055\u308c\u307e\u3059 (\u904a\u96e2\u304a\u3088\u3073\u5171\u5f79\u5316\u5408\u7269\u306e\u5f62\u3067)…\u5b9f\u9a13\u505c\u6b62\u304b\u3089 72 \u6642\u9593\u5f8c\u306b\u306f\u3001\u653e\u5c04\u80fd\u306f 4.3% \u306e\u30ec\u30d9\u30eb\u3067\u3057\u304b\u5b58\u5728\u3057\u306a\u304f\u306a\u308a\u307e\u3057\u305f\u3002\u5c3f<\/a><\/span>\u4e2d\u306b1.9\uff05\u3001\u7cde\u4fbf\u4e2d\u306b1.9\uff05\u3002<\/p>

\u30e9\u30c3\u30c8\u306e\u5834\u5408\u3001\u6442\u53d6\u6642\u306b\u6700\u3082\u5f71\u97ff\u3092\u53d7\u3051\u308b\u306e\u306f\u809d\u81d3\u3067\u3042\u308b\u3068\u8003\u3048\u3089\u308c\u307e\u3059\u3002<\/p>