{"id":3288,"date":"2024-03-30T15:40:21","date_gmt":"2024-03-30T15:40:21","guid":{"rendered":"https:\/\/science-hub.click\/1%2C4-%E3%83%99%E3%83%B3%E3%82%BE%E3%82%AD%E3%83%8E%E3%83%B3%E3%81%AB%E3%81%A4%E3%81%84%E3%81%A6%E8%A9%B3%E3%81%97%E3%81%8F%E8%A7%A3%E8%AA%AC\/"},"modified":"2024-03-30T15:40:21","modified_gmt":"2024-03-30T15:40:21","slug":"1%2C4-%E3%83%99%E3%83%B3%E3%82%BE%E3%82%AD%E3%83%8E%E3%83%B3%E3%81%AB%E3%81%A4%E3%81%84%E3%81%A6%E8%A9%B3%E3%81%97%E3%81%8F%E8%A7%A3%E8%AA%AC","status":"publish","type":"post","link":"https:\/\/science-hub.click\/?p=3288","title":{"rendered":"1,4-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3\u306b\u3064\u3044\u3066\u8a73\u3057\u304f\u89e3\u8aac"},"content":{"rendered":"

\u5c0e\u5165<\/h2>
1,4-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3<\/th><\/tr>
\u4e00\u822c\u7684\u306a<\/th><\/tr>
IUPAC\u540d<\/td><\/tr>
\u540c\u7fa9\u8a9e<\/td>p-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3p-\u30ad\u30ce\u30f3<\/td><\/tr>
CAS\u756a\u53f7<\/sup><\/td>106-51-4<\/span><\/span><\/td><\/tr>
No.EINECS<\/sup><\/td> 203-405-2<\/span><\/td><\/tr>
\u30d1\u30d6\u30b1\u30e0<\/td>4650<\/span><\/td><\/tr>
\u7b11\u9854<\/td><\/tr>
\u30a4\u30f3\u30c1\u30c1<\/td><\/tr>
\u5916\u89b3<\/td>\u523a\u6fc0\u81ed\u306e\u3042\u308b\u9ec4\u8272\u306e\u7d50\u6676\u307e\u305f\u306f\u9ec4\u8272\u306e<\/a><\/span>\u56fa\u4f53\u3002\u5ba4\u6e29<\/a><\/span>\u3067\u3082\u6607\u83ef\u3057\u307e\u3059\u3002<\/td><\/tr>
\u5316\u5b66\u7684\u6027\u8cea<\/th><\/tr>
\u751f\u306e\u30d5\u30a9\u30fc\u30df\u30e5\u30e9<\/td>C6H4O2<\/sub>\u200b<\/sub>\u200b<\/sub><\/td><\/tr>
\u30e2\u30eb\u8cea\u91cf<\/a><\/span><\/td>108.0948 \u00b1 0.0057 g\u30fbmol -1<\/sup><\/td><\/tr>
\u7269\u7406\u7684\u6027\u8cea<\/th><\/tr>
\u878d\u89e3<\/a><\/span>\u6e29\u5ea6<\/td>115.7<\/span> \u2103<\/abbr><\/td><\/tr>
\u6cb8\u9a30<\/a><\/span>\u6e29\u5ea6<\/td>+\/- 108<\/span> \u00b0C<\/abbr><\/td><\/tr>
\u6eb6\u89e3\u6027<\/td>10g<\/span>\u30fb<\/span>l<\/sup> -1<\/span><\/span> (\u6c34\u3001 25<\/span> \u2103<\/abbr> )<\/td><\/tr>
\u5bc6\u5ea6<\/a><\/span><\/td>1.32<\/span> g<\/span> cm<\/span> -3<\/sup><\/span> ( 20<\/span> \u00b0C)<\/abbr><\/td><\/tr>
\u81ea\u7136\u767a\u706b\u6e29\u5ea6<\/td>560<\/span> \u2103<\/abbr><\/td><\/tr>
\u5f15\u706b\u70b9<\/a><\/span><\/td>38<\/span> \uff5e 93<\/span> \u2103<\/span><\/span><\/td><\/tr>
\u71b1\u5316\u5b66<\/a><\/span><\/th><\/tr>
\u0394H0<\/sup><\/td> -186.8kJ<\/span>\u30fbmol<\/span> –<\/sup> 1<\/span><\/span><\/td><\/tr>
\u0394H\u00b0<\/td> 112.85<\/span> \u00b0C<\/abbr>\u306718.45<\/span> kJ<\/span> \u00b7 mol<\/span> -1<\/sup><\/span><\/td><\/tr>
CP<\/sub><\/td> 126.4<\/span> J<\/span> K<\/span> -1<\/sup> mol<\/span> -1<\/sup><\/span> ( 25<\/span> \u00b0C<\/abbr> \u3001\u56fa\u4f53) 107.37<\/span> J<\/span> K<\/span> -1<\/sup> mol<\/span> -1<\/sup><\/span> ( 25<\/span> \u00b0C<\/abbr> \u3001\u30ac\u30b9)<\/td><\/tr>
PCI<\/td> -2,725.8<\/span> kJ<\/span>\u30fbmol<\/span> -1<\/sup><\/span><\/td><\/tr>
\u96fb\u5b50\u7269\u6027<\/th><\/tr>
1\u6b21<\/sup>\u30a4\u30aa\u30f3\u5316<\/a><\/span>\u30a8\u30cd\u30eb\u30ae\u30fc<\/a><\/span><\/td>10.01<\/span> \u00b1 0.06 eV<\/span><\/span> (\u30ac\u30b9)<\/td><\/tr>
\u4e88\u9632<\/th><\/tr>
\u6307\u4ee4 67\/548\/EEC <\/center><\/td><\/tr>
\n\"\u6709\u6bd2\"<\/figure> T <\/center><\/td>
\n\"\u74b0\u5883\u306b\u3068\u3063\u3066\u5371\u967a\"<\/figure> N<\/center><\/td><\/tr><\/table><\/td><\/tr>
R\u30d5\u30ec\u30fc\u30ba\uff1a 23\/25\u300136<\/span> \/37\/<\/span> 38\u300150\u3001<\/span><\/td><\/tr>
S\u30d5\u30ec\u30fc\u30ba\uff1a<\/span> \uff08 1\/2<\/span> \uff09\u3001<\/span> 26\u300128\u300145\u300161<\/span> \u3001<\/span><\/td><\/tr>
\u4ea4\u901a\u6a5f\u95a2<\/a><\/span><\/center><\/td><\/tr>
60<\/span><\/center><\/td><\/tr>
2587<\/span><\/center><\/td><\/tr><\/table><\/center><\/td><\/tr>
NFPA 704<\/center><\/td><\/tr>
2<\/span><\/div>
3<\/span><\/div>
0<\/span><\/div><\/div><\/td><\/tr>
GHS <\/center><\/td><\/tr>
\n\"SGH06:<\/figure>
\n\"SGH09:<\/figure>\u5371\u967a<\/center>H301\u3001<\/span> H315\u3001<\/span> H319\u3001<\/span> H331\u3001<\/span> H335\u3001<\/span> H400\u3001<\/span><\/td><\/tr>
IARC \u5206\u985e<\/center><\/td><\/tr>
\u30b0\u30eb\u30fc\u30d7 3:\u30d2\u30c8<\/a><\/span>\u306b\u5bfe\u3059\u308b\u767a\u304c\u3093\u6027\u306b\u3064\u3044\u3066\u306f\u5206\u985e\u3067\u304d\u306a\u3044<\/td><\/tr>
\u751f\u614b\u6bd2\u6027\u5b66<\/th><\/tr>
DL<\/td> 8.5<\/span> mg<\/span>\u30fbkg<\/span> -1<\/sup><\/span> (\u30de\u30a6\u30b9\u3001\u7d4c\u53e3) 130<\/span> mg<\/span>\u30fbkg<\/span> -1<\/sup><\/span> (\u30e9\u30c3\u30c8\u3001\u7d4c\u53e3)<\/td><\/tr>
\u30ed\u30b0P<\/td> 0.2<\/td><\/tr>
\u5302\u3044\u306e\u95be\u5024<\/td>\u4f4e: 0.1<\/span> ppm<\/span><\/span>\u9ad8: 0.15<\/span> ppm<\/span><\/span><\/td><\/tr>
\u95a2\u9023\u5316\u5408\u7269<\/th><\/tr>
\u7570\u6027\u4f53<\/td>1,2-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3<\/td><\/tr>
\u305d\u306e\u4ed6\u306e\u5316\u5408\u7269<\/td>\u30d7\u30e9\u30b9\u30c8\u30ad\u30ce\u30f3<\/td><\/tr>
\u7279\u306b\u6307\u5b9a\u306e<\/a><\/span>\u306a\u3044\u9650\u308a\u3001SI \u304a\u3088\u3073 CNTP \u5358\u4f4d\u3002<\/center><\/td><\/tr><\/table>

1,4-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3<\/b>\u307e\u305f\u306f\u30b7\u30af\u30ed\u30d8\u30ad\u30b5-2,5-\u30b8\u30a8\u30f3-1,4-\u30b8\u30aa\u30f3<\/b>\u306f\u3001\u5316\u5b66\u5f0f C 6<\/sub> H 4<\/sub> O 2<\/sub>\u306e\u30b1\u30c8\u30f3<\/a><\/span>\u3067\u3059\u3002\u3053\u308c\u306f\u30ad\u30ce\u30f3\u306e 2 \u3064\u306e\u7570\u6027\u4f53\u306e\u3046\u3061\u306e 1 \u3064\u3067\u3042\u308a\u3001\u3082\u3046 1 \u3064\u306f 1,2-\u30d9\u30f3\u30be\u30ad\u30ce\u30f3\u3067\u3059\u3002\u3053\u306e\u975e\u82b3\u9999\u65cf\u5316\u5408\u7269\u306f\u3001\u30cf\u30a4\u30c9\u30ed\u30ad\u30ce\u30f3<\/a><\/span>(\u30d9\u30f3\u30bc\u30f3-1,4-\u30b8\u30aa\u30fc\u30eb) \u306e\u9178\u5316\u8a98\u5c0e\u4f53\u3067\u3059\u3002\u3053\u306e\u5206\u5b50\u306f<\/a><\/span>\u30b1\u30c8\u30f3\u3068\u30a2\u30eb\u30b1\u30f3<\/a><\/span>\u306e\u6027\u8cea\u3092\u6301\u3063\u3066\u3044\u307e\u3059\u3002<\/p>

\u4f7f\u7528<\/h2>

\u3053\u306e\u5206\u5b50\u306f\u3001\u6709\u6a5f<\/span>\u5408\u6210\u306b\u304a\u3044\u3066\u30d7\u30ed\u30c8\u30f3<\/a><\/span>\u53d7\u5bb9\u4f53\u304a\u3088\u3073\u9178\u5316\u5264\u3068\u3057\u3066\u4f7f\u7528\u3055\u308c\u307e\u3059\u3002\u30c7\u30a3\u30fc\u30eb\u30b9\u30fb\u30a2\u30eb\u30c0\u30fc\u53cd\u5fdc\u306b\u304a\u3044\u3066\u30b8\u30a8\u30ce\u30d5\u30a3\u30eb\u3068\u3057\u3066\u4f7f\u7528\u3059\u308b\u3053\u3068\u3082\u3067\u304d\u307e\u3059\u3002\u4ee5\u4e0b\u306e\u7269\u8cea\u3092\u5408\u6210\u3059\u308b\u305f\u3081\u306e\u4e2d\u9593\u4f53\u3068\u3057\u3066\u4f7f\u7528\u3055\u308c\u307e\u3059\u3002<\/p>