{"id":4993,"date":"2024-07-16T19:25:21","date_gmt":"2024-07-16T19:25:21","guid":{"rendered":"https:\/\/science-hub.click\/%E3%83%A8%E3%82%A6%E5%8C%96%E3%82%B5%E3%83%9E%E3%83%AA%E3%82%A6%E3%83%A0%28II%29%E3%81%AB%E3%81%A4%E3%81%84%E3%81%A6%E8%A9%B3%E3%81%97%E3%81%8F%E8%A7%A3%E8%AA%AC\/"},"modified":"2024-07-16T19:25:21","modified_gmt":"2024-07-16T19:25:21","slug":"%E3%83%A8%E3%82%A6%E5%8C%96%E3%82%B5%E3%83%9E%E3%83%AA%E3%82%A6%E3%83%A0%28II%29%E3%81%AB%E3%81%A4%E3%81%84%E3%81%A6%E8%A9%B3%E3%81%97%E3%81%8F%E8%A7%A3%E8%AA%AC","status":"publish","type":"post","link":"https:\/\/science-hub.click\/?p=4993","title":{"rendered":"\u30e8\u30a6\u5316\u30b5\u30de\u30ea\u30a6\u30e0(II)\u306b\u3064\u3044\u3066\u8a73\u3057\u304f\u89e3\u8aac"},"content":{"rendered":"

\u5c0e\u5165<\/h2>
\u30e8\u30a6\u5316\u30b5\u30de\u30ea\u30a6\u30e0(II)<\/th><\/tr>
\n\"SmI2\u3068THF\u306e\u932f\u4f53\uff1aSmI2(THF)5\"<\/figure><\/td><\/tr>
\u4e00\u822c\u7684\u306a<\/th><\/tr>
IUPAC\u540d<\/td><\/tr>
CAS\u756a\u53f7<\/sup><\/td>32248-43-4<\/span><\/span><\/td><\/tr>
\u30d1\u30d6\u30b1\u30e0<\/td>24865638<\/span><\/td><\/tr>
\u5916\u89b3<\/td>\u7dd1\u8272\u306e\u7c89<\/a><\/span><\/td><\/tr>
\u5316\u5b66\u7684\u6027\u8cea<\/th><\/tr>
\u751f\u306e\u30d5\u30a9\u30fc\u30df\u30e5\u30e9<\/td>I 2<\/sub> Sm<\/span> SmI 2<\/sub><\/td><\/tr>
\u30e2\u30eb\u8cea\u91cf<\/a><\/span><\/td>404.17 \u00b1 0.02 g\u30fbmol -1<\/sup><\/td><\/tr>
\u7269\u7406\u7684\u6027\u8cea<\/th><\/tr>
\u878d\u89e3<\/a><\/span>\u6e29\u5ea6<\/td>520<\/span> \u2103<\/abbr><\/td><\/tr>
\u5f15\u706b\u70b9<\/a><\/span><\/td>\u4e0d\u71c3\u6027<\/td><\/tr>
\u7279\u306b\u6307\u5b9a\u306e<\/a><\/span>\u306a\u3044\u9650\u308a\u3001SI \u304a\u3088\u3073 CNTP \u5358\u4f4d\u3002<\/center><\/td><\/tr><\/table>

\u30e8\u30a6\u5316\u30b5\u30de\u30ea\u30a6\u30e0(II)<\/b> \u3001SmI 2<\/sub>\u306f\u3001\u30b5\u30de\u30ea\u30a6\u30e0<\/a><\/span>\u3068\u30e8\u30a6\u7d20<\/a><\/span>\u3067\u69cb\u6210\u3055\u308c\u308b\u7dd1\u8272\u306e<\/a><\/span>\u56fa\u4f53\u3067\u3001 520<\/span> \u00b0C<\/abbr>\u3067\u878d\u89e3\u3057\u3001\u30b5\u30de\u30ea\u30a6\u30e0\u539f\u5b50\u306f<\/a><\/span>\u30ad\u30e3\u30c3\u30d7\u4ed8\u304d\u516b\u9762\u4f53<\/a><\/span>\u69cb\u9020\u306e 7 \u96a3\u63a5\u914d\u4f4d\u7403<\/a><\/span>\u3092\u6301\u3061\u307e\u3059\u3002\u3053\u308c\u306f\u3001\u6700\u3082\u5b89\u5b9a\u306a\u30e8\u30a6\u5316\u30b5\u30de\u30ea\u30a6\u30e0\u3067\u3042\u308b SmI 3<\/sub>\u306e\u9ad8\u6e29<\/a><\/span>\u5206\u89e3<\/a><\/span>\u306b\u3088\u3063\u3066\u751f\u6210\u3067\u304d\u307e\u3059\u304c\u3001\u5b9f\u9a13\u5ba4\u3067\u306e\u3088\u308a\u4fbf\u5229\u306a\u8abf\u88fd\u65b9\u6cd5\u306f\u3001\u7121\u6c34 THF \u4e2d\u3067\u30b5\u30de\u30ea\u30a6\u30e0\u7c89\u672b\u30681,2-\u30b8\u30e8\u30fc\u30c9\u30a8\u30bf\u30f3<\/span>\u3092\u53cd\u5fdc\u3055\u305b\u308b\u3053\u3068\u3067\u3059\u3002<\/p>

Sm + ICH 2<\/sub> CH 2<\/sub> I \u2192 SmI 2<\/sub> + C 2<\/sub> H 4<\/sub><\/dd><\/dl>

\u30b8\u30e8\u30fc\u30c9\u30e1\u30bf\u30f3<\/span>(CH 2<\/sub> I 2<\/sub> ) \u3082\u4f7f\u7528\u3067\u304d\u307e\u3059\u3002 SmI 2<\/sub>\u306f\u3001THF \u4e2d\u306e 0.1 M \u6fc3\u9752\u8272<\/a><\/span>\u6eb6\u6db2\u3068\u3057\u3066\u3082\u5e02\u8ca9\u3055\u308c\u3066\u3044\u307e\u3059\u3002<\/p>

\u30e8\u30a6\u5316\u30b5\u30de\u30ea\u30a6\u30e0\u306f\u5f37\u529b\u306a\u9084\u5143\u5264\u3067\u3059\u3002\u305f\u3068\u3048\u3070\u3001\u6c34\u3092<\/a><\/span>\u3059\u3050\u306b\u6c34\u7d20<\/a><\/span>\u306b\u9084\u5143\u3057\u307e\u3059\u3002<\/p>

\u53cd\u5fdc<\/h2>

\u30e8\u30a6\u5316\u30b5\u30de\u30ea\u30a6\u30e0(II)\u306f\u3001\u4f8b\u3048\u3070\u30b1\u30c8\u30f3<\/a><\/span>\u3068\u30cf\u30ed\u30b2\u30f3\u5316\u30a2\u30eb\u30ad\u30eb\u306e\u9593\u306e\u30d0\u30eb\u30d3\u30a8\u53cd\u5fdc(\u30b0\u30ea\u30cb\u30e3\u30fc\u30eb\u53cd\u5fdc\u306b\u4f3c\u305f)\u306b\u3088\u308b\u70ad\u7d20-\u70ad\u7d20\u7d50\u5408\u5f62\u6210\u306e\u305f\u3081\u306e\u4e00\u822c\u7684\u306a\u8a66\u85ac\u3068\u306a\u308a\u3001\u30a2\u30eb\u30b3\u30fc\u30eb\u7b2c\u4e09\u7d1a\u3092\u5f62\u6210\u3057\u307e\u3059\u3002<\/p>

R 1<\/sup> X + R 2<\/sup> COR 3<\/sup> \u2192 R 1<\/sup> R 2<\/sup> C(OH)R 3<\/sup><\/dd><\/dl>
\n\"\"<\/figure>
SmI 2 \u3092<\/sub>\u4f7f\u7528\u3057\u305f\u30d0\u30eb\u30d3\u30a8\u53cd\u5fdc\u306e\u7d44\u307f\u7acb\u3066<\/div><\/div><\/div>

\u5178\u578b\u7684\u306a\u53cd\u5fdc\u30d7\u30ed\u30c8\u30b3\u30eb\u3067\u306f\u3001\u89e6\u5a92\u91cf<\/a><\/span>\u306e\u30e8\u30a6\u5316\u30cb\u30c3\u30b1\u30eb(II)<\/span> (NiI 2<\/sub> ) \u306e\u5b58\u5728\u4e0b\u3001THF \u4e2d\u306e SmI 2 \u3092<\/sub>\u4f7f\u7528\u3057\u307e\u3059\u3002<\/p>

\u30a8\u30b9\u30c6\u30eb\u3082\u540c\u69d8\u306b\u53cd\u5fdc\u3057\u307e\u3059\u304c\uff082 \u3064\u306e R \u57fa\u306e\u4ed8\u52a0\uff09\u3001\u30a2\u30eb\u30c7\u30d2\u30c9\u304c\u526f\u751f\u6210\u7269\u3092\u5f62\u6210\u3057\u307e\u3059\u3002\u3053\u306e\u53cd\u5fdc\u306f\u591a\u304f\u306e\u5834\u5408\u975e\u5e38\u306b\u8fc5\u901f\u3067\u3042\u308b\u305f\u3081 (\u51b7\u5374\u6642\u9593\u306f 5\u5206<\/span>\u4ee5\u5185)\u3001\u4fbf\u5229\u3067\u3059\u3002\u30e8\u30a6\u5316\u30b5\u30de\u30ea\u30a6\u30e0(II)\u306f\u5f37\u529b\u306a\u4e00\u96fb\u5b50<\/a><\/span>\u9084\u5143\u5264\u3067\u3042\u308b\u3068\u8003\u3048\u3089\u308c\u3066\u3044\u307e\u3059\u304c\u3001\u5b98\u80fd\u57fa\u9593\u3067\u9855\u8457\u306a\u5316\u5b66\u9078\u629e\u6027\u3092\u793a\u3057\u307e\u305b\u3093\u3002\u305f\u3068\u3048\u3070\u3001\u30b9\u30eb\u30db\u30f3\u304a\u3088\u3073\u30b9\u30eb\u30db\u30ad\u30b7\u30c9\u306f\u3001\u30a8\u30b9\u30c6\u30eb\u3001\u30b1\u30c8\u30f3\u3001\u30a2\u30df\u30c9\u3001\u30a2\u30eb\u30c7\u30d2\u30c9\u306a\u3069\u306e\u4ed6\u306e\u591a\u304f\u306e\u30ab\u30eb\u30dc\u30cb\u30eb\u57fa\u306e\u5b58\u5728\u4e0b\u3067\u3001\u5bfe\u5fdc\u3059\u308b\u30b9\u30eb\u30d5\u30a3\u30c9<\/a><\/span>\u306b\u9084\u5143\u3067\u304d\u307e\u3059\u3002\u3053\u308c\u306f\u3001S=O \u7d50\u5408\u3068\u6bd4\u8f03\u3057\u3066 C=0 \u4e8c\u91cd\u7d50\u5408\u3067\u306e\u53cd\u5fdc\u304c\u304b\u306a\u308a\u9045\u3044<\/a><\/span>\u305f\u3081\u3068\u8003\u3048\u3089\u308c\u307e\u3059\u3002\u3055\u3089\u306b\u3001\u30cf\u30ed\u30b2\u30f3\u5316\u30a2\u30eb\u30ad\u30eb\u306e\u5bfe\u5fdc\u3059\u308b\u70ad\u5316\u6c34\u7d20\u3078\u306e\u6c34\u7d20\u5316\u8131\u30cf\u30ed\u30b2\u30f3\u5316\u3082\u3001SmI 2<\/sub>\u3092\u7528\u3044\u3066\u884c\u3046\u3053\u3068\u304c\u3067\u304d\u308b\u3002\u3053\u308c\u3089\u306e\u53cd\u5fdc\u306b\u7d9a\u3044\u3066\u3001\u53cd\u5fdc\u304c\u8d77\u3053\u308b\u3068\u3001THF\u4e2d\u306eSmI 2<\/sub>\u6eb6\u6db2\u306e\u6fc3\u9752\u8272\u304b\u3089\u6de1\u9ec4\u8272<\/a><\/span>\u3078\u306e\u8272<\/a><\/span>\u5909\u5316\u304c\u8d77\u3053\u308b\u53ef\u80fd\u6027\u304c\u3042\u308b\u3002\u5b9f\u969b\u3001\u53cd\u5bfe\u306e\u753b\u50cf\u306b\u898b\u3089\u308c\u308b\u3088\u3046\u306b\u3001\u6697\u3044\u8272\u306f\u30d0\u30eb\u30d3\u30a8\u53cd\u5fdc\u6df7\u5408\u7269<\/a><\/span>\u3068\u63a5\u89e6\u3059\u308b\u3068\u3059\u3050\u306b\u6d88\u3048\u307e\u3059\u3002<\/p>

\u6b21\u3044\u3067\u3001\u53cd\u5fdc\u6df7\u5408\u7269\u3092\u5e0c\u5869\u9178<\/a><\/span>\u3067\u51e6\u7406\u3057\u3001\u30b5\u30de\u30ea\u30a6\u30e0\u3092\u6c34\u6027\uff33\uff4d \uff13\uff0b<\/sup>\u30a4\u30aa\u30f3\u3068\u3057\u3066\u9664\u53bb\u3059\u308b\u3002<\/p>

\u30ab\u30eb\u30dc\u30cb\u30eb<\/a><\/span>\u5316\u5408\u7269\u306f\u3001\u5358\u7d14\u306a\u30a2\u30eb\u30b1\u30f3\u3068\u7d50\u5408\u3057\u3066\u30015\u30016\u3001\u307e\u305f\u306f 8 \u539f\u5b50\u306e\u74b0\u3092\u5f62\u6210\u3059\u308b\u3053\u3068\u3082\u3067\u304d\u307e\u3059\u3002<\/p>

\u30c8\u30b7\u30eb\u57fa\u306f\u3001SmI 2 \u3092<\/sub>\u5869\u57fa\u3068\u7d44\u307f\u5408\u308f\u305b\u3066\u4f7f\u7528\u200b\u200b\u3059\u308b\u3068\u3001 N<\/i> -\u30c8\u30b7\u30eb\u30a2\u30df\u30c9\u304a\u3088\u3073\u30c8\u30b7\u30eb\u9178\u30a8\u30b9\u30c6\u30eb\u304b\u3089\u307b\u307c\u77ac\u6642\u306b\u9664\u53bb\u3067\u304d\u307e\u3059\u3002\u3053\u306e\u53cd\u5fdc\u306f\u3001\u30a2\u30b8\u30ea\u30b8\u30f3\u306a\u3069\u306e\u654f\u611f\u306a\u30a2\u30df\u30f3\u306e\u5408\u6210\u306b\u3082\u52b9\u679c\u7684\u3067\u3059\u3002<\/p>

\n\"\"<\/figure>
SmI 2<\/sub>\u3092\u4f7f\u7528\u3057\u305fN<\/i> -\u30c8\u30b7\u30eb\u30a2\u30df\u30c9\u304b\u3089\u306e\u30c8\u30b7\u30eb\u57fa\u306e\u9664\u53bb<\/div><\/div><\/div><\/dd><\/dl>

\u30de\u30eb\u30b3-\u30e9\u30e0\u8131\u9178\u7d20\u3067\u306f\u3001SmI 2<\/sub>\u306e\u5b58\u5728\u4e0b\u3067\u30a2\u30eb\u30b3\u30fc\u30eb\u306e\u30c8\u30eb\u30a4\u30eb\u9178\u30a8\u30b9\u30c6\u30eb<\/a><\/span>\u3092\u9084\u5143\u3059\u308b\u3053\u3068\u306b\u3088\u308a\u3001\u30a2\u30eb\u30b3\u30fc\u30eb\u3092\u307b\u307c\u77ac\u6642\u306b\u8131\u9178\u7d20\u3067\u304d\u307e\u3059\u3002<\/p>

\n\"\"<\/figure>
SmI 2<\/sub>\u3092\u4f7f\u7528\u3057\u305f\u30de\u30eb\u30b3-\u30e9\u30e0\u8131\u9178\u7d20<\/div><\/div><\/div><\/dd><\/dl>

\u30e8\u30a6\u5316\u30b5\u30de\u30ea\u30a6\u30e0(II)\u306e\u5fdc\u7528\u306f\u7dcf\u8aac\u8a18\u4e8b\u306e\u4e3b\u984c<\/span>\u3068\u306a\u3063\u3066\u3044\u307e\u3059\u3002<\/p><\/div>

\u53c2\u8003\u8cc7\u6599<\/h2>
  1. \u0633\u0627\u0645\u0627\u0631\u06cc\u0648\u0645 (II) \u06cc\u0648\u062f\u06cc\u0648\u062f \u2013 South Azerbaijani<\/a><\/li>
  2. Jodid samarnat\u00fd \u2013 tch\u00e8que<\/a><\/li>
  3. Samarium(II)-iodid \u2013 allemand<\/a><\/li>
  4. Samarium(II) iodide \u2013 anglais<\/a><\/li>
  5. Samaria (II) jodido \u2013 esp\u00e9ranto<\/a><\/li>
  6. \u0633\u0627\u0645\u0627\u0631\u06cc\u0645 (II) \u06cc\u062f\u06cc\u062f \u2013 persan<\/a><\/li><\/ol><\/div>\n
    \n

    \n \u30e8\u30a6\u5316\u30b5\u30de\u30ea\u30a6\u30e0(II)\u306b\u3064\u3044\u3066\u8a73\u3057\u304f\u89e3\u8aac\u30fb\u95a2\u9023\u52d5\u753b\n <\/h2>\n
    \n \n
    \n
    \n