{"id":66975,"date":"2024-08-02T15:59:25","date_gmt":"2024-08-02T15:59:25","guid":{"rendered":"https:\/\/science-hub.click\/%E3%83%98%E3%82%AD%E3%82%B5%E3%83%A1%E3%83%81%E3%83%AB%E3%83%9B%E3%82%B9%E3%83%9B%E3%83%AB%E3%82%A2%E3%83%9F%E3%83%89%E3%81%AB%E3%81%A4%E3%81%84%E3%81%A6%E8%A9%B3%E3%81%97%E3%81%8F%E8%A7%A3%E8%AA%AC\/"},"modified":"2024-08-02T15:59:25","modified_gmt":"2024-08-02T15:59:25","slug":"%E3%83%98%E3%82%AD%E3%82%B5%E3%83%A1%E3%83%81%E3%83%AB%E3%83%9B%E3%82%B9%E3%83%9B%E3%83%AB%E3%82%A2%E3%83%9F%E3%83%89%E3%81%AB%E3%81%A4%E3%81%84%E3%81%A6%E8%A9%B3%E3%81%97%E3%81%8F%E8%A7%A3%E8%AA%AC","status":"publish","type":"post","link":"https:\/\/science-hub.click\/?p=66975","title":{"rendered":"\u30d8\u30ad\u30b5\u30e1\u30c1\u30eb\u30db\u30b9\u30db\u30eb\u30a2\u30df\u30c9\u306b\u3064\u3044\u3066\u8a73\u3057\u304f\u89e3\u8aac"},"content":{"rendered":"

\u5c0e\u5165<\/h2>
\u30d8\u30ad\u30b5\u30e1\u30c1\u30eb\u30db\u30b9\u30db\u30eb\u30a2\u30df\u30c9<\/th><\/tr>
\u4e00\u822c\u7684\u306a<\/th><\/tr>
\u540c\u7fa9\u8a9e<\/td>\u30d8\u30ad\u30b5\u30e1\u30bf\u30dd\u30fc\u30ebHMPA(\u82f1\u8a9e) HMPT<\/td><\/tr>
CAS\u756a\u53f7<\/sup><\/td>680-31-9<\/span><\/span><\/td><\/tr>
No.EINECS<\/sup><\/td> 211-653-8<\/span><\/td><\/tr>
\u7b11\u9854<\/td><\/tr>
\u30a4\u30f3\u30c1\u30c1<\/td><\/tr>
\u5916\u89b3<\/td>\u7279\u5fb4\u7684\u306a\u81ed\u6c17\u306e\u3042\u308b\u3001\u7121\u8272\u306e\u6d41\u52d5\u6027\u306e\u6db2\u4f53<\/a><\/span>\u3002<\/td><\/tr>
\u5316\u5b66\u7684\u6027\u8cea<\/th><\/tr>
\u751f\u306e\u30d5\u30a9\u30fc\u30df\u30e5\u30e9<\/td>C6H18N3OP<\/sub>\u200b<\/sub>\u200b<\/sub><\/td><\/tr>
\u30e2\u30eb\u8cea\u91cf<\/a><\/span><\/td>179.2004 \u00b1 0.007 g mol -1<\/sup><\/td><\/tr>
\u5206\u5b50\u5f84<\/a><\/span><\/td>0.702nm<\/span><\/span><\/span><\/td><\/tr>
\u7269\u7406\u7684\u6027\u8cea<\/th><\/tr>
\u878d\u89e3<\/a><\/span>\u6e29\u5ea6<\/td>7.2<\/span> \u2103<\/abbr><\/td><\/tr>
\u6cb8\u9a30<\/a><\/span>\u6e29\u5ea6<\/td>232.5<\/span> \u2103<\/abbr><\/td><\/tr>
\u6eb6\u89e3\u6027<\/td>1000g<\/span>\u30fbl<\/span> –<\/sup> 1<\/span><\/span> (\u6c34)<\/td><\/tr>
\u5bc6\u5ea6<\/a><\/span><\/td>1.03g<\/span>\u30fb<\/span>cm<\/span> -3<\/sup><\/span><\/td><\/tr>
\u5f15\u706b\u70b9<\/a><\/span><\/td>105<\/span> \u2103<\/abbr><\/td><\/tr>
\u98fd\u548c\u84b8\u6c17\u5727<\/a><\/span><\/td>0.046mmHg<\/span> 25<\/span><\/span> \u2103<\/span>\u200b<\/abbr><\/td><\/tr>
\u4e88\u9632<\/th><\/tr>
\u6307\u4ee4 67\/548\/EEC <\/center><\/td><\/tr>
\n\"\u6709\u6bd2\"<\/figure> T<\/center><\/td><\/tr><\/table><\/td><\/tr>
R\u30d5\u30ec\u30fc\u30ba\uff1a 45\u300146<\/span> \u3001<\/span><\/td><\/tr>
S\u30d5\u30ec\u30fc\u30ba\uff1a 45\u300153<\/span> \u3001<\/span><\/td><\/tr>
WHMIS <\/center><\/td><\/tr>
\n\"D2A:<\/figure><\/center> D2A\u3001<\/span><\/td><\/tr>
GHS<\/center><\/td><\/tr>
\u5371\u967a<\/center>H340\u3001<\/span> H350\u3001<\/span><\/td><\/tr>
IARC \u5206\u985e<\/center><\/td><\/tr>
\u30b0\u30eb\u30fc\u30d7 2B:\u30d2\u30c8<\/a><\/span>\u306b\u5bfe\u3057\u3066\u767a\u304c\u3093\u6027\u304c<\/a><\/span>\u3042\u308b\u53ef\u80fd\u6027\u304c\u3042\u308b<\/td><\/tr>
\u751f\u614b\u6bd2\u6027\u5b66<\/th><\/tr>
DL<\/td> 2,400<\/span> mg<\/span>\u30fbkg<\/span> -1<\/sup><\/span> (\u30de\u30a6\u30b9\u3001\u7d4c\u53e3) 800<\/span> mg<\/span> \u00b7 kg<\/span> -1<\/sup><\/span> (\u30de\u30a6\u30b9\u3001\u9759\u8108\u5185) 1,600<\/span> mg<\/span>\u30fbkg<\/span> -1<\/sup><\/span> (\u30de\u30a6\u30b9\u3001\u8179\u8154\u5185)<\/td><\/tr>
\u7279\u306b\u6307\u5b9a\u306e<\/a><\/span>\u306a\u3044\u9650\u308a\u3001SI \u304a\u3088\u3073 CNTP \u5358\u4f4d\u3002<\/center><\/td><\/tr><\/table>

\u30d8\u30ad\u30b5\u30e1\u30c1\u30eb\u30db\u30b9\u30db\u30eb\u30a2\u30df\u30c9<\/b>\u3001\u7565\u79f0 HMPA (HMPT = \u30d8\u30ad\u30b5\u30e1\u30c1\u30eb\u30db\u30b9\u30db\u30ed\u30c8\u30ea\u30a2\u30df\u30c9\u3068\u306f\u7570\u306a\u308a\u307e\u3059) \u306f\u3001\u5316\u5b66\u5f0f C 6<\/sub> H 18<\/sub> N 3<\/sub> PO \u3092\u6301\u3064\u7121\u8272\u306e\u6709\u6a5f<\/span>\u6db2\u4f53\u3067\u3059\u3002<\/p>

\n\"\u30d8\u30ad\u30b5\u30e1\u30c1\u30eb\u30db\u30b9\u30db\u30eb\u30a2\u30df\u30c9\u306b\u3064\u3044\u3066\u8a73\u3057\u304f\u89e3\u8aac\"<\/figure>

\u4e00\u822c\u7684\u306a<\/h2>

\u3053\u308c\u306f\u3001\u5b9f\u9a13\u5ba4\u306b\u304a\u3051\u308b\u30dd\u30ea\u30de\u30fc\u6eb6\u5a92<\/a><\/span>\u3001\u30ac\u30b9<\/a><\/span>\u306e\u9078\u629e\u6eb6\u5a92\u3001\u30dd\u30ea\u30b9\u30c1\u30ec\u30f3<\/a><\/span>\u306e\u71b1<\/a><\/span>\u52a3\u5316\u9632\u6b62\u5264\u3001\u6709\u6a5f\u91d1\u5c5e\u304a\u3088\u3073\u305d\u306e\u4ed6\u306e\u6709\u6a5f\u53cd\u5fdc\u306e\u6eb6\u5a92\u3068\u3057\u3066\u4f7f\u7528\u3055\u308c\u307e\u3059\u3002\u8a66\u9a13\u306b\u3088\u308a\u3001\u6d88\u706b\u7269\u8cea\u304a\u3088\u3073\u6606\u866b<\/a><\/span>\u5316\u5b66\u6bba\u83cc\u5264\u3068\u3057\u3066\u306e\u6709\u52b9\u6027\u304c\u8a3c\u660e\u3055\u308c\u3066\u3044\u307e\u3059\u304c\u3001\u73fe\u6642\u70b9\u3067\u306f\u3001\u3069\u3061\u3089\u306e\u7528\u9014\u306b\u3082\u3053\u306e\u88fd\u54c1\u304c\u4f7f\u7528\u3055\u308c\u305f\u3053\u3068\u306f\u77e5\u3089\u308c\u3066\u3044\u307e\u305b\u3093\u3002\u7279\u5b9a\u306e\u53cd\u5fdc\u306e\u9078\u629e\u6027\u3092\u5411\u4e0a\u3055\u305b\u308b\u306e\u306b\u975e\u5e38\u306b\u5f79\u7acb\u3061\u307e\u3059\u3002\u305f\u3068\u3048\u3070\u3001\u30d7\u30ed\u30c8\u30f3\u5316\u53cd\u5fdc\u4e2d\u306b\u3001HMPT \u306f\u30d6\u30c1\u30eb \u30ea\u30c1\u30a6\u30e0\u306a\u3069\u306e\u5869\u57fa\u6027\u30ea\u30c1\u30a6\u30e0<\/a><\/span>\u30aa\u30ea\u30b4\u30de\u30fc\u3092\u5206\u89e3\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3059\u3002 HMPA \u306f\u3001\u30a2\u30cb\u30aa\u30f3\u3092\u6eb6\u5a92\u548c\u305b\u305a\u306b\u30ab\u30c1\u30aa\u30f3\u3092\u6eb6\u5a92\u548c\u3059\u308b\u80fd\u529b\u304c\u3042\u308b\u305f\u3081\u3001\u7279\u306b\u7e4a\u7d30\u306a SN2 \u53cd\u5fdc\u3092\u5b9f\u884c\u3059\u308b\u305f\u3081\u306e\u6eb6\u5a92\u3068\u3057\u3066\u4f7f\u7528\u3055\u308c\u307e\u3059\u3002\u5869\u57fa\u6027\u9178\u7d20\u306f\u3001<\/a><\/span> Li +<\/sup>\u30ab\u30c1\u30aa\u30f3\u3092\u3088\u304f\u6eb6\u5a92\u548c\u3057\u307e\u3059\u3002 HMPA \u306f\u3001\u6700\u3082\u5869\u57fa\u6027\u306e\u7b2c\u4e09\u7d1a\u30db\u30b9\u30d5\u30a3\u30f3<\/a><\/span>P(NMe 2<\/sub> ) 3<\/sub>\u306e\u9178\u5316\u7269<\/a><\/span>\u3067\u3059\u3002\u307b\u3068\u3093\u3069\u306e\u30db\u30b9\u30d5\u30a3\u30f3\u30aa\u30ad\u30b7\u30c9 (\u30c8\u30ea\u30d5\u30a7\u30cb\u30eb\u30db\u30b9\u30d5\u30a3\u30f3\u30aa\u30ad\u30b7\u30c9\u306a\u3069) \u3068\u540c\u69d8\u306b\u3001\u3053\u306e\u5206\u5b50\u306f<\/a><\/span>\u56db\u9762\u4f53\u30b3\u30a2\u3092\u6301\u3061\u3001PO \u7d50\u5408\u306f\u975e\u5e38\u306b\u5206\u6975\u3057\u3066\u3044\u307e\u3059\u3002\u3057\u305f\u304c\u3063\u3066\u3001\u9178\u7d20\u306b\u5b58\u5728\u3059\u308b\u8ca0\u96fb\u8377<\/a><\/span>\u306f\u91cd\u8981\u3067\u3059\u3002<\/p>

\u6bd2\u6027<\/h2>

HMPA \u306f\u305d\u308c\u307b\u3069\u6bd2\u6027\u306f\u3042\u308a\u307e\u305b\u3093\u304c\u3001\u4f9d\u7136\u3068\u3057\u3066<\/a><\/span>\u30e9\u30c3\u30c8<\/a><\/span>\u306e\u9f3b\u764c\u306e\u539f\u56e0\u3067\u3042\u308b\u3068\u8003\u3048\u3089\u308c\u3066\u3044\u307e\u3059\u3002\u3055\u3089\u306b\u3001\u5869\u9178<\/a><\/span>\u306e\u4f5c\u7528\u306b\u3088\u308a\u3001\u6bd2\u6027\u306e\u4f4e\u3044\u5316\u5408\u7269\u306b\u5206\u89e3\u3055\u308c\u307e\u3059\u3002<\/p>

\u4ee3\u66ff\u8a66\u85ac<\/h2>

\u30b8\u30e1\u30c1\u30eb\u30b9\u30eb\u30db\u30ad\u30b7\u30c9<\/a><\/span>(DMSO) \u306f\u3001HMPA \u306e\u4ee3\u308f\u308a\u306e\u6eb6\u5a92\u3068\u3057\u3066\u3088\u304f\u4f7f\u7528\u3055\u308c\u307e\u3059\u3002\u3053\u308c\u3089\u306e\u5316\u5408\u7269\u306f\u3069\u3061\u3089\u3082\u5f37\u529b\u306a\u6c34\u7d20\u7d50\u5408<\/a><\/span>\u30a2\u30af\u30bb\u30d7\u30bf\u30fc\u90e8\u4f4d\u3092\u793a\u3057\u3001\u305d\u308c\u3089\u306e\u9178\u7d20\u306f\u91d1\u5c5e\u30ab\u30c1\u30aa\u30f3\u3068\u7d50\u5408\u3092\u5f62\u6210\u3059\u308b\u3053\u3068\u304c\u3067\u304d\u307e\u3059\u3002<\/p><\/div>

\u53c2\u8003\u8cc7\u6599<\/h2>
  1. \u0647\u0642\u0632\u0627\u0645\u062a\u06cc\u0644\u0641\u0648\u0633\u0641\u0648\u0631\u0622\u0645\u06cc\u062f \u2013 South Azerbaijani<\/a><\/li>
  2. Hexamethylfosforamid \u2013 tch\u00e8que<\/a><\/li>
  3. Hexamethylphosphors\u00e4uretriamid \u2013 allemand<\/a><\/li>
  4. Hexamethylphosphoramide \u2013 anglais<\/a><\/li>
  5. Hexametilfosforamida \u2013 espagnol<\/a><\/li>
  6. \u0647\u06af\u0632\u0627\u0645\u062a\u06cc\u0644\u200c\u0641\u0633\u0641\u0631\u0622\u0645\u06cc\u062f \u2013 persan<\/a><\/li><\/ol><\/div>\n
    \n

    \n \u30d8\u30ad\u30b5\u30e1\u30c1\u30eb\u30db\u30b9\u30db\u30eb\u30a2\u30df\u30c9\u306b\u3064\u3044\u3066\u8a73\u3057\u304f\u89e3\u8aac\u30fb\u95a2\u9023\u52d5\u753b\n <\/h2>\n
    \n \n
    \n
    \n