{"id":87193,"date":"2024-02-12T19:38:36","date_gmt":"2024-02-12T19:38:36","guid":{"rendered":"https:\/\/science-hub.click\/1%2C1-%E3%82%B8%E3%83%A1%E3%83%81%E3%83%AB%E3%83%92%E3%83%89%E3%83%A9%E3%82%B8%E3%83%B3%E3%81%AB%E3%81%A4%E3%81%84%E3%81%A6%E8%A9%B3%E3%81%97%E3%81%8F%E8%A7%A3%E8%AA%AC\/"},"modified":"2024-02-12T19:38:36","modified_gmt":"2024-02-12T19:38:36","slug":"1%2C1-%E3%82%B8%E3%83%A1%E3%83%81%E3%83%AB%E3%83%92%E3%83%89%E3%83%A9%E3%82%B8%E3%83%B3%E3%81%AB%E3%81%A4%E3%81%84%E3%81%A6%E8%A9%B3%E3%81%97%E3%81%8F%E8%A7%A3%E8%AA%AC","status":"publish","type":"post","link":"https:\/\/science-hub.click\/?p=87193","title":{"rendered":"1,1-\u30b8\u30e1\u30c1\u30eb\u30d2\u30c9\u30e9\u30b8\u30f3\u306b\u3064\u3044\u3066\u8a73\u3057\u304f\u89e3\u8aac"},"content":{"rendered":"

\u5c0e\u5165<\/h2>
\n\"\"<\/figure>
1998 \u5e74 11 \u6708 20 \u65e5\u306b\u3001\u904e\u9178\u5316\u7a92\u7d20 (NTO) \u3092\u542b\u3080\u7d14\u7c8b\u306a UDMH \u3067\u63a8\u9032\u3055\u308c\u308b\u30d7\u30ed\u30c8\u30f3 K \u30ed\u30b1\u30c3\u30c8\u306b\u3088\u3063\u3066\u3001ISS \u306e\u30b6\u30ea\u30e4 \u30e2\u30b8\u30e5\u30fc\u30eb\u304c\u6253\u3061\u4e0a\u3052\u3089\u308c\u307e\u3057\u305f\u3002 <\/div><\/div><\/div>
\u30b8\u30e1\u30c1\u30eb\u30d2\u30c9\u30e9\u30b8\u30f3<\/th><\/tr>
\n\"\u30b8\u30e1\u30c1\u30eb\u30d2\u30c9\u30e9\u30b8\u30f3\u306e\u7acb\u4f53\u69cb\u9020\"<\/figure><\/td><\/tr>
\u4e00\u822c\u7684\u306a<\/th><\/tr>
IUPAC\u540d<\/td><\/tr>
\u540c\u7fa9\u8a9e<\/td>\u30b8\u30e1\u30c1\u30eb\u30d2\u30c9\u30e9\u30b8\u30f3N,N-\u30b8\u30e1\u30c1\u30eb\u30d2\u30c9\u30e9\u30b8\u30f3\u30d2\u30c9\u30e9\u30b8\u30f3<\/td><\/tr>
CAS\u756a\u53f7<\/sup><\/td>57-14-7<\/span><\/span><\/td><\/tr>
No.EINECS<\/sup><\/td> 200-316-0<\/span><\/td><\/tr>
\u30d1\u30d6\u30b1\u30e0<\/td>5976<\/span><\/td><\/tr>
\u7b11\u9854<\/td><\/tr>
\u30a4\u30f3\u30c1\u30c1<\/td><\/tr>
\u5916\u89b3<\/td>\u5438\u6e7f\u6027\u306e\u6db2\u4f53<\/a><\/span>\u3001\u7121\u8272\u3001\u767a\u7159\u6027\u3001\u523a\u6fc0\u81ed\u306e\u3042\u308b\u6db2\u4f53\u3002\u7a7a\u6c17<\/a><\/span>\u306b\u89e6\u308c\u308b\u3068\u9ec4\u8272<\/a><\/span>\u306b\u306a\u308a\u307e\u3059\u3002<\/td><\/tr>
\u5316\u5b66\u7684\u6027\u8cea<\/th><\/tr>
\u751f\u306e\u30d5\u30a9\u30fc\u30df\u30e5\u30e9<\/td>C2H8N2<\/sub>\u200b<\/sub>\u200b<\/sub><\/td><\/tr>
\u30e2\u30eb\u8cea\u91cf<\/a><\/span><\/td>60.0983 \u00b1 0.0026 g mol -1<\/sup><\/td><\/tr>
\u7269\u6027<\/th><\/tr>
\u878d\u89e3<\/a><\/span>\u6e29\u5ea6<\/td>-58<\/span> \u2103<\/abbr><\/td><\/tr>
\u6cb8\u9a30<\/a><\/span>\u6e29\u5ea6<\/td>63<\/span> \u2103<\/abbr><\/td><\/tr>
\u6eb6\u89e3\u6027<\/td>\u6c34\u4e2d\uff1a\u975e\u5e38\u306b\u826f\u3044<\/td><\/tr>
\u5bc6\u5ea6<\/a><\/span><\/td>(\u6c34=1):0.8<\/td><\/tr>
\u81ea\u7136\u767a\u706b\u6e29\u5ea6<\/td>240<\/span> \u2103<\/abbr><\/td><\/tr>
\u5f15\u706b\u70b9<\/a><\/span><\/td>-15<\/span> \u00b0C<\/abbr> (\u5bc6\u9589\u30ab\u30c3\u30d7)\u3001 -18<\/span> \u2103<\/abbr><\/td><\/tr>
\u7a7a\u6c17\u4e2d\u3067\u306e\u7206\u767a\u9650\u754c<\/td>2.4<\/span> \u2013 20<\/span> %vol<\/span><\/span> 60<\/span> \uff5e 490g<\/span>\u30fb<\/span>m<\/span> -3<\/sup><\/span><\/td><\/tr>
\u98fd\u548c\u84b8\u6c17\u5727<\/a><\/span><\/td>20<\/span> \u2103<\/abbr>\u6642\uff1a<\/span> 16.4kPa<\/span><\/span><\/td><\/tr>
\u71b1\u5316\u5b66<\/a><\/span><\/th><\/tr>
S0<\/sup><\/td> 200.25<\/span> JK<\/span> -1<\/sup>\u30e2\u30eb<\/span>-1<\/sup>\u200b<\/span><\/span><\/td><\/tr>
\u0394H0<\/sup><\/td> 83.3kJ<\/span>\u30fb<\/span>mol<\/span> -1<\/sup><\/span><\/td><\/tr>
\u0394H0<\/sup><\/td> 48.3kJ<\/span>\u30fbmol<\/span> –<\/sup> 1<\/span><\/span><\/td><\/tr>
\u0394H\u00b0<\/td> -57.2<\/span> \u00b0C<\/abbr>\u306710.0726<\/span> kJ<\/span> \u00b7 mol<\/span> -1<\/sup><\/span><\/td><\/tr>
\u0394H\u00b0<\/td> 35.55<\/span> kJ<\/span>\u30fbmol<\/span> -1<\/sup><\/span> ( 63.05<\/span> \u00b0C)<\/abbr><\/td><\/tr>
CP<\/sub><\/td> 164.05<\/span> J<\/span> K<\/span> -1<\/sup> mol<\/span> -1<\/sup><\/span> ( 25<\/span> \u00b0C)<\/abbr><\/td><\/tr>
PCI<\/td> 1,977.6kJ<\/span>\u30fb<\/span>mol<\/span> -1<\/sup><\/span><\/td><\/tr>
\u96fb\u5b50\u7269\u6027<\/th><\/tr>
1\u6b21<\/sup>\u30a4\u30aa\u30f3\u5316<\/a><\/span>\u30a8\u30cd\u30eb\u30ae\u30fc<\/a><\/span><\/td>7.29<\/span> \u00b1 0.05 eV<\/span><\/span> (\u30ac\u30b9)<\/td><\/tr>
\u4e88\u9632<\/th><\/tr>
\u6307\u4ee4 67\/548\/EEC <\/center><\/td><\/tr>
\n\"\u6709\u6bd2\"<\/figure> T <\/center><\/td>
\n\"\u5f15\u706b\u6027\u304c\u9ad8\u3044\"<\/figure> F <\/center><\/td>
\n\"\u74b0\u5883\u306b\u3068\u3063\u3066\u5371\u967a\"<\/figure> N<\/center><\/td><\/tr><\/table><\/td><\/tr>
R<\/span>\u30d5\u30ec\u30fc\u30ba\uff1a 11\u300123<\/span> \/25\u300134\u300145\u300151<\/span> \/ 53<\/span> \u3001<\/span><\/td><\/tr>
S\u30d5\u30ec\u30fc\u30ba\uff1a<\/span> 45\u300153\u300161<\/span> \u3001<\/span><\/td><\/tr>
\u4ea4\u901a\u6a5f\u95a2<\/a><\/span><\/center><\/td><\/tr>
663<\/span><\/center><\/td><\/tr>
1163<\/span><\/center><\/td><\/tr><\/table><\/center><\/td><\/tr>
NFPA 704<\/center><\/td><\/tr>
3<\/span><\/div>
4<\/span><\/div>
1<\/span><\/div><\/div><\/td><\/tr>
WHMIS <\/center><\/td><\/tr>
\n\"B2:<\/figure>
\n\"D1A:<\/figure>
\n\"E\uff1a\u8150\u98df\u6027\u7269\u8cea\"<\/figure><\/center> B2\u3001<\/span> D1A\u3001<\/span> D2A\u3001<\/span> E\u3001<\/span><\/td><\/tr>
GHS\u3002 <\/center><\/td><\/tr>
\n\"SGH02:<\/figure>\u5371\u967a<\/center>H225\u3001<\/span> H301\u3001<\/span> H314\u3001<\/span> H331\u3001<\/span> H350\u3001<\/span> H411\u3001<\/span><\/td><\/tr>
IARC \u5206\u985e<\/center><\/td><\/tr>
\u30b0\u30eb\u30fc\u30d7 2B:\u30d2\u30c8<\/a><\/span>\u306b\u5bfe\u3057\u3066\u767a\u304c\u3093\u6027\u304c<\/a><\/span>\u3042\u308b\u53ef\u80fd\u6027\u304c\u3042\u308b<\/td><\/tr>
\u751f\u614b\u6bd2\u6027\u5b66<\/th><\/tr>
DL<\/td> 122<\/span> mg<\/span>\u30fbkg<\/span> -1<\/sup><\/span> (\u30e9\u30c3\u30c8\u3001\u7d4c\u53e3) 155<\/span> mg<\/span>\u30fbkg<\/span> -1<\/sup><\/span> (\u30de\u30a6\u30b9\u3001\u7d4c\u53e3)<\/td><\/tr>
\u30ed\u30b0P<\/td> -1.9<\/td><\/tr>
\u5302\u3044\u306e\u95be\u5024<\/td>\u4f4e: 6.1<\/span> ppm<\/span><\/span>\u9ad8: 14<\/span> ppm<\/span><\/span><\/td><\/tr>
\u7279\u306b\u6307\u5b9a\u306e<\/a><\/span>\u306a\u3044\u9650\u308a\u3001SI \u304a\u3088\u3073 CNTP \u5358\u4f4d\u3002<\/center><\/td><\/tr><\/table>

1,1-\u30b8\u30e1\u30c1\u30eb\u30d2\u30c9\u30e9\u30b8\u30f3\u306f<\/b>\u3001\u5b87\u5b99\u5b66<\/a><\/span>\u3067\u306fUDMH<\/b> \uff08\u975e\u5bfe\u79f0\u30b8\u30e1\u30c1\u30eb\u30d2\u30c9\u30e9\u30b8\u30f3<\/b>\u306e\u7565\u3001\u82f1\u8a9e\u3067\u306fUn<\/b>\u5bfe\u79f0<\/b>\u30b8\u30e1\u30c1\u30eb\u30d2\u30c9\u30e9\u30b8\u30f3<\/b>\uff09<\/b><\/i>\u3068\u547c\u3070\u308c\u3001\u5f0fH 2<\/sub> NN(CH 3<\/sub> ) 2<\/sub>\u306e\u5316\u5408\u7269\u3067\u3059\u3002 UDMH \u306f\u3001\u6709\u6a5f\u30a2\u30df\u30f3\u306b\u7279\u6709\u306e\u523a\u6fc0\u7684\u306a\u30a2\u30f3\u30e2\u30cb\u30a2\u81ed\u3092\u6301\u3064\u3001\u900f\u660e\u3067\u63ee\u767a\u6027\u306e\u5438\u6e7f\u6027\u6db2\u4f53\u306e\u5f62\u614b\u3067\u3059\u3002\u5c4b\u5916\u3067\u306f\u9178\u7d20<\/a><\/span>\u3068\u4e8c\u9178\u5316\u70ad\u7d20\u3092<\/a><\/span>\u5438\u53ce\u3057\u3001\u9ec4\u8272\u306b\u5909\u308f\u308a\u307e\u3059\u3002\u6c34<\/a><\/span>\u3001\u30a8\u30bf\u30ce\u30fc\u30eb\u3001\u706f\u6cb9<\/a><\/span>\u3068\u3042\u3089\u3086\u308b\u5272\u5408\u3067\u6df7\u548c\u3057\u307e\u3059\u3002<\/p>

UDMH \u306f\u885d\u6483\u3067\u306f\u7206\u767a\u3057\u307e\u305b\u3093\u304c\u3001\u305d\u306e\u84b8\u6c17\u306f\u7a7a\u6c17\u4e2d\u306e 2.5 \uff5e 95%<\/span>\u306e\u6fc3\u5ea6\u3067\u53ef\u71c3\u6027\u3067\u3059\u3002\u30a2\u30a8\u30ed\u30b8\u30f3 50 \u3084 UH 25 \u306a\u3069\u306e\u30ed\u30b1\u30c3\u30c8\u7528\u306e\u591a\u304f\u306e\u6db2\u4f53\u63a8\u9032\u5264\u306e\u7d44\u6210\u306b\u4f7f\u7528\u3055\u308c\u3001\u904e<\/a><\/span>\u9178\u5316\u7a92\u7d20<\/a><\/span>N 2<\/sub> O 4<\/sub> (NTO) \u3068 MON (\u7a92\u7d20\u306e\u904e\u9178\u5316\u7269\u3068\u4e00\u9178\u5316\u7269\u306e\u3055\u307e\u3056\u307e\u306a\u5272\u5408\u306e\u6df7\u5408\u7269) \u3092\u542b\u3080\u9ad8\u6fc3\u5ea6<\/a><\/span>\u63a8\u9032\u5264<\/span>\u3092\u5f62\u6210\u3057\u307e\u3059<\/a><\/span>\u3002\u6291\u5236\u8d64\u8272<\/a><\/span>\u767a\u7159\u785d\u9178<\/a><\/span>(IRFNA) \u3092\u307e\u3060\u4f7f\u7528\u3057\u3066\u3044\u307e\u3059\u3002<\/p>

UDMH \u306f\u3001\u9ad8\u6e29\u3067\u306e\u6319\u52d5\u304c\u826f\u304f\u3001\u7206\u767a<\/a><\/span>\u306e\u5371\u967a\u6027\u304c\u4f4e\u304f\u3001\u4f4e\u6e29<\/a><\/span>\u3067\u306f\u6db2\u4f53\u3067\u3042\u308b\u305f\u3081 (\u30d2\u30c9\u30e9\u30b8\u30f3\u306e1<\/span> \u00b0C<\/abbr>\u3067\u306f\u306a\u304f-57<\/span> \u00b0C<\/abbr>\u3067\u51cd\u7d50\u3057\u307e\u3059)\u3001\u9084\u5143\u63a8\u9032\u5264<\/a><\/span>\u3068\u3057\u3066\u7d14\u7c8b\u306a\u30d2\u30c9\u30e9\u30b8\u30f3\u3088\u308a\u3082\u597d\u307e\u308c\u307e\u3057\u305f\u3002\u5b87\u5b99\u8239\u306e\u30bf\u30f3\u30af\u306b\u9577\u671f\u9593<\/a><\/span>\u4fdd\u5b58\u3067\u304d\u307e\u3059\u3002\u307e\u305f\u3001\u975e\u5e38\u306b\u5bc6\u5ea6\u304c\u9ad8\u3044\uff08 793<\/span> kg<\/span>\u30fbm<\/span> -3<\/sup><\/span> \u3001\u30d2\u30c9\u30e9\u30b8\u30f3\uff1a 1,004.5<\/span> kg<\/span>\u30fbm<\/span> -3<\/sup><\/span>\u3088\u308a\u5c0f\u3055\u3044\uff09\u305f\u3081\u3001\u5b87\u5b99\u63a8\u9032<\/span>\u306b\u512a\u308c\u305f\u6027\u80fd\u3092\u767a\u63ee\u3057\u307e\u3059\u3002
<\/p>

UDMH \u306f\u30d2\u30c9\u30e9\u30b8\u30f3\u3092 50 \u8cea\u91cf\uff05\u6df7\u5408\u3059\u308b\u3068\u30a8\u30a2\u30ed\u30b8\u30f3 50 \u3068\u547c\u3070\u308c\u308b\u71c3\u6599<\/a><\/span>\u306b\u306a\u308a\u3001\u30d2\u30c9\u30e9\u30b8\u30f3\u306e\u9ad8\u5bc6\u5ea6<\/a><\/span>\u3068 UDMH \u306e\u5b89\u5b9a\u6027\u3092\u517c\u306d\u5099\u3048\u3066\u3044\u307e\u3059\u3002 UDMH \u304c\u6700\u3082\u3088\u304f\u4f7f\u7528\u3055\u308c\u308b\u306e\u306f\u3001\u30a8\u30a2\u30ed\u30b8\u30f3 50 \u306e\u5f62\u5f0f\u3067\u3059\u3002<\/p>

\u4e2d\u56fd\u306e\u9577\u5f81<\/a><\/span>(NTO \u3068\u5354\u529b)\u3001\u30ed\u30b7\u30a2\u306e\u30b3\u30b9\u30e2\u30b9 (IRFNA \u3068\u5354\u529b)\u3001\u30ed\u30b7\u30a2\u306e\u30d7\u30ed\u30c8\u30f3<\/a><\/span>(NTO \u3068\u5354\u529b)\u3001\u30b7\u30e3\u30d3\u30c3\u30c8 \u30a4\u30b9\u30e9\u30a8\u30eb (NTO \u3068\u5354\u529b) \u306a\u3069\u3001\u591a\u304f\u306e\u767a\u5c04\u6a5f\u306f\u7d14\u7c8b\u306a UDMH \u307e\u305f\u306f Aerozine 50 \u3092\u642d\u8f09\u3057\u3066\u3044\u307e\u3059\u3002\u30a2\u30e1\u30ea\u30ab\u30f3 \u30c7\u30eb\u30bf (NTO \u4ed8\u304d a\u00e9rozine 50)\u3001\u307e\u305f\u306f\u5c06\u6765\u306e\u30a4\u30f3\u30c7\u30a3\u30a2\u30f3 GSLV Mk III (NTO \u4ed8\u304d) \u3067\u3059\u3002<\/p><\/div>

\u53c2\u8003\u8cc7\u6599<\/h2>
  1. \u062a\u0639\u0631\u064a\u0641 \u2013 arabe<\/a><\/li>
  2. T\u0259rif (m\u0259ntiq) \u2013 azerba\u00efdjanais<\/a><\/li>
  3. \u0414\u0435\u0444\u0438\u043d\u0438\u0446\u0438\u044f \u2013 bulgare<\/a><\/li>
  4. \u09b8\u0982\u099c\u09cd\u099e\u09be \u2013 bengali<\/a><\/li>
  5. \u0f58\u0f5a\u0f53\u0f0b\u0f49\u0f72\u0f51\u0f0d \u2013 tib\u00e9tain<\/a><\/li>
  6. Termenadur \u2013 breton<\/a><\/li><\/ol><\/div>\n
    \n

    \n 1,1-\u30b8\u30e1\u30c1\u30eb\u30d2\u30c9\u30e9\u30b8\u30f3\u306b\u3064\u3044\u3066\u8a73\u3057\u304f\u89e3\u8aac\u30fb\u95a2\u9023\u52d5\u753b\n <\/h2>\n
    \n \n
    \n
    \n