{"id":94343,"date":"2024-07-14T18:29:03","date_gmt":"2024-07-14T18:29:03","guid":{"rendered":"https:\/\/science-hub.click\/%E3%83%86%E3%83%88%E3%83%A9%E3%83%81%E3%82%A2%E3%83%95%E3%83%AB%E3%83%90%E3%83%AC%E3%83%B3%E3%81%AB%E3%81%A4%E3%81%84%E3%81%A6%E8%A9%B3%E3%81%97%E3%81%8F%E8%A7%A3%E8%AA%AC\/"},"modified":"2024-07-14T18:29:03","modified_gmt":"2024-07-14T18:29:03","slug":"%E3%83%86%E3%83%88%E3%83%A9%E3%83%81%E3%82%A2%E3%83%95%E3%83%AB%E3%83%90%E3%83%AC%E3%83%B3%E3%81%AB%E3%81%A4%E3%81%84%E3%81%A6%E8%A9%B3%E3%81%97%E3%81%8F%E8%A7%A3%E8%AA%AC","status":"publish","type":"post","link":"https:\/\/science-hub.click\/?p=94343","title":{"rendered":"\u30c6\u30c8\u30e9\u30c1\u30a2\u30d5\u30eb\u30d0\u30ec\u30f3\u306b\u3064\u3044\u3066\u8a73\u3057\u304f\u89e3\u8aac"},"content":{"rendered":"

\u5c0e\u5165<\/h2>
\u30c6\u30c8\u30e9\u30c1\u30a2\u30d5\u30eb\u30d0\u30ec\u30f3<\/th><\/tr>
\n\"\u30c6\u30c8\u30e9\u30c1\u30a2\u30d5\u30eb\u30d0\u30ec\u30f3\u306e\u69cb\u9020\"<\/figure><\/td><\/tr>
\u4e00\u822c\u7684\u306a<\/th><\/tr>
IUPAC\u540d<\/td><\/tr>
\u540c\u7fa9\u8a9e<\/td>\u03942,2′-\u30d3-1,3-\u30b8\u30c1\u30aa\u30fc\u30eb\u3001TTF<\/td><\/tr>
CAS\u756a\u53f7<\/sup><\/td>31366-25-3<\/span><\/span><\/td><\/tr>
No.EINECS<\/sup><\/td> 250-593-7<\/span><\/td><\/tr>
\u30d1\u30d6\u30b1\u30e0<\/td>99451<\/span><\/td><\/tr>
\u7b11\u9854<\/td><\/tr>
\u30a4\u30f3\u30c1\u30c1<\/td><\/tr>
\u5916\u89b3<\/td>\u30aa\u30ec\u30f3\u30b8\u8272\u306e\u7d50\u6676<\/td><\/tr>
\u5316\u5b66\u7684\u6027\u8cea<\/th><\/tr>
\u751f\u306e\u30d5\u30a9\u30fc\u30df\u30e5\u30e9<\/td>C6H4S4<\/sub>\u200b<\/sub>\u200b<\/sub><\/td><\/tr>
\u30e2\u30eb\u8cea\u91cf<\/a><\/span><\/td>204.356 \u00b1 0.025 g mol -1<\/sup><\/td><\/tr>
\u7269\u7406\u7684\u6027\u8cea<\/th><\/tr>
\u878d\u89e3<\/a><\/span>\u6e29\u5ea6<\/td>190.1<\/span> \uff5e 191.3<\/span> \u2103<\/abbr><\/td><\/tr>
\u71b1\u5316\u5b66<\/a><\/span><\/th><\/tr>
\u0394H0<\/sup><\/td> 290.8kJ<\/span>\u30fbmol<\/span> –<\/sup> 1<\/span><\/span><\/td><\/tr>
PCI<\/td> -5,619.5<\/span> kJ<\/span>\u30fbmol<\/span> -1<\/sup><\/span><\/td><\/tr>
\u4e88\u9632<\/th><\/tr>
NFPA 704<\/center><\/td><\/tr>
0<\/span><\/div>
1<\/span><\/div>
0<\/span><\/div><\/div><\/td><\/tr>
WHMIS<\/center><\/td><\/tr>
\u7ba1\u7406\u3055\u308c\u3066\u3044\u306a\u3044\u88fd\u54c1<\/td><\/tr>
\u7279\u306b\u6307\u5b9a\u306e<\/a><\/span>\u306a\u3044\u9650\u308a\u3001SI \u304a\u3088\u3073 CNTP \u5358\u4f4d\u3002<\/center><\/td><\/tr><\/table>

\u30c6\u30c8\u30e9\u30c1\u30a2\u30d5\u30eb\u30d0\u30ec\u30f3<\/b>(\u4e00\u822c\u306bTTF<\/b>\u3068\u7565\u8a18\u3055\u308c\u307e\u3059) \u306f\u3001<\/sub>\u5f0fH2C2S2C<\/sub> = CS2C2H2<\/sub>\u3067\u8868\u3055\u308c\u308b\u786b\u9ec4<\/a><\/span>\u542b\u6709<\/sub>\u8907\u7d20<\/sub>\u74b0\u5f0f\u5316\u5408\u7269\u3067\u3059<\/sub>\u3002\u3053\u308c\u306f\u3001\u96fb\u5b50\u4f9b\u4e0e\u4f53 ( p<\/i>\u578b\u5316\u5408\u7269) \u3068\u3057\u3066\u5206\u5b50\u30a8\u30ec\u30af\u30c8\u30ed\u30cb\u30af\u30b9\u306e\u5206\u91ce\u3067\u3001\u7279\u306b TCNQ \u3068\u5f62\u6210\u3059\u308b\u96fb\u8377<\/a><\/span>\u79fb\u52d5\u932f\u4f53\u306b\u95a2\u3057\u3066\u96c6\u4e2d\u7684\u306b\u7814\u7a76\u3055\u308c\u3066\u3044\u307e\u3059\u3002 TTF \u3068\u305d\u306e\u8a98\u5c0e\u4f53\u306f\u7279\u306b\u30d9\u30d2\u30ac\u30fc\u30c9\u5869\u3092\u5f62\u6210\u3057\u3001\u4f4e\u6e29\u3067\u8d85\u96fb\u5c0e\u4f53\u306b\u306a\u308a\u307e\u3059\u3002\u3053\u308c\u306f\u7279\u306b TMTSF (\u30c6\u30c8\u30e9\u30e1\u30c1\u30eb\u30c6\u30c8\u30e9\u30bb\u30ec\u30ca\u30d5\u30eb\u30d0\u30ec\u30f3) \u3068 BEDT-TTF (\u30d3\u30b9(\u30a8\u30c1\u30ec\u30f3\u30b8\u30c1\u30aa)-\u30c6\u30c8\u30e9\u30c1\u30a2\u30d5\u30eb\u30d0\u30ec\u30f3) \u306b\u5f53\u3066\u306f\u307e\u308a\u307e\u3059\u3002 1 \u4e07\u3092\u8d85\u3048\u308b\u79d1\u5b66\u51fa\u7248\u7269\u304c TTF \u3068\u305d\u306e\u6d3e\u751f\u7269\u3092\u6271\u3063\u3066\u3044\u307e\u3059\u3002<\/p>

\n\"\u30c6\u30c8\u30e9\u30c1\u30a2\u30d5\u30eb\u30d0\u30ec\u30f3\u306b\u3064\u3044\u3066\u8a73\u3057\u304f\u89e3\u8aac\"<\/figure>

\u6e96\u5099<\/h2>

TTF \u3068\u305d\u306e\u8a98\u5c0e\u4f53\u306b\u5bfe\u3059\u308b\u95a2\u5fc3\u306b\u3088\u308a\u3001\u3053\u306e\u5206\u5b50<\/a><\/span>\u3068\u305d\u306e\u985e\u4f3c\u4f53\u306e\u3044\u304f\u3064\u304b\u306e\u5408\u6210\u6cd5\u304c\u958b\u767a\u3055\u308c\u307e\u3057\u305f\u3002\u3053\u308c\u3089\u306e\u8abf\u88fd\u306e\u307b\u3068\u3093\u3069\u306f\u30011,3-\u30b8\u30c1\u30aa\u30fc\u30eb-2-\u30c1\u30aa\u30f3\u307e\u305f\u306f\u95a2\u9023\u3059\u308b1,3-\u30b8\u30c1\u30aa\u30fc\u30eb-2-\u30aa\u30f3\u306a\u3069\u306e\u74b0\u72b6C 3<\/sub> S 2<\/sub>\u6838\u3092\u6709\u3059\u308b\u5206\u5b50\u306e\u30ab\u30c3\u30d7\u30ea\u30f3\u30b0\u3092\u5fc5\u8981\u3068\u3057\u307e\u3059\u3002 TTF \u306e\u5834\u5408\u3001\u5408\u6210\u306f\u30c8\u30ea\u30c1\u30aa\u30ab\u30fc\u30dc\u30cd\u30fc\u30c8 H 2<\/sub> C 2<\/sub> S 2<\/sub> C=S \u304b\u3089\u59cb\u307e\u308a\u3001\u6700\u521d\u306b S-\u30e1\u30c1\u30eb\u5316\u3055\u308c\u3001\u6b21\u306b\u30c6\u30c8\u30e9<\/a><\/span>\u30d5\u30eb\u30aa\u30ed\u30dc\u30ec\u30fc\u30c8\u6c34\u7d20<\/span>HBF 4<\/sub>\u3067\u51e6\u7406\u3055\u308c\u3001\u6700\u5f8c\u306b\u30c8\u30ea\u30a8\u30c1\u30eb\u30a2\u30df\u30f3\u3067\u51e6\u7406\u3055\u308c\u307e\u3059\u3002<\/p>

H 2<\/sub> C 2<\/sub> S 2<\/sub> CH(SCH 3<\/sub> ) + HBF 4<\/sub> \u2192 [H 2<\/sub> C 2<\/sub> S 2<\/sub> CH +<\/sup> ]BF 4<\/sub> –<\/sup> + HSCH 3<\/sub><\/dd><\/dl>
2 [H 2<\/sub> C 2<\/sub> S 2<\/sub> CH +<\/sup> ]BF 4<\/sub> –<\/sup> + 2 Et 3<\/sub> N \u2192 H 2<\/sub> C 2<\/sub> S 2<\/sub> C=CS 2<\/sub> C 2<\/sub> H 2<\/sub> + 2 Et 3<\/sub> NHBF 4<\/sub><\/dd><\/dl><\/div>
\n\"\u30c6\u30c8\u30e9\u30c1\u30a2\u30d5\u30eb\u30d0\u30ec\u30f3\u306b\u3064\u3044\u3066\u8a73\u3057\u304f\u89e3\u8aac\"<\/figure>

\u53c2\u8003\u8cc7\u6599<\/h2>
  1. Tetrathiafulvalen \u2013 tch\u00e8que<\/a><\/li>
  2. Tetrathiafulvalen \u2013 allemand<\/a><\/li>
  3. Tetrathiafulvalene \u2013 anglais<\/a><\/li>
  4. Tetratiafulvaleno \u2013 espagnol<\/a><\/li>
  5. \u062a\u062a\u0631\u0627\u062a\u06cc\u0627\u0641\u0648\u0644\u0648\u0627\u0644\u0646 \u2013 persan<\/a><\/li>
  6. Tetratiafulvalene \u2013 italien<\/a><\/li><\/ol><\/div>\n
    \n

    \n \u30c6\u30c8\u30e9\u30c1\u30a2\u30d5\u30eb\u30d0\u30ec\u30f3\u306b\u3064\u3044\u3066\u8a73\u3057\u304f\u89e3\u8aac\u30fb\u95a2\u9023\u52d5\u753b\n <\/h2>\n
    \n \n
    \n
    \n